内容简介

Ionic Liquid in Process Intensification explores the applications of ionic liquids for process intensification research;focuses on computational simulation methods of ionic liquids, their structural design, regulation, and interaction; describes process intensification reactions, separation, photo/ electrochemistry, and material synthesis related to ionic liquids. 

Ionic Liquid in Process Intensification’s combination of computational chemistry, physical chemistry, chemical engineering, materials science, and many other basic and applied disciplines makes it a key reference for scientists, technical personnel, teachers, and students in chemical engineering, chemistry, materials science, energy, and environment science.

目录

1. Introduction
1.1 Brief introduction of ionic liquids and the understanding of nanomicrostructures
1.2 Nanostructure regulation and process intensification of ionic liquids
1.3 Conclusion and perspective
References
2. Interaction and interface of ionic liquids
2.1 Overview
2.2 Methods for simulating ionic liquid structures
2.3 Simulation study of ionic liquid structures in the interface
2.4 Simulation and regulation of two-dimensional ionic liquids
2.5 Prediction and control of ionic liquid structures
References
3. Ionic liquids intensify reaction process
3.1 Overview
3.2 Ionic liquids regulate homogeneous catalysis reaction
3.3 The multiphase reaction based on ionic liquids
3.4 Bioionic liquids: tunable microenvironment for biocatalysis
3.5 Ionic liquids intensified biomass conversion
References
4. Ionic liquids intensify separation process
4.1 Overview
4.2 Ionic liquids intensify gas separation
4.3 Application of ionic liquids in liquid2liquid extraction
4.4 Ionic liquids for protein and protein complex extraction
4.5 Membrane separation process with ionic liquids
References
5. Photo- and electrochemical process with ionic liquids
5.1 Overview
5.2 Photocatalytic and photoelectrocatalytic process with ionic liquids
5.3 Application of ionic liquids in solar cells
5.4 Ionic liquids intensify the electrochemistry process
5.5 Application of ionic liquids in new energy batteries
References
6. Synthesis of ionic liquid-based materials
6.1 Overview
6.2 Preparation of nanomaterials with ionic liquids
6.3 Ionic liquids intensify the synthesis of molecular sieve materials
6.4 Synthesis of ionic liquid-based metal organic complexes
6.5 Synthesis and application of polymerized ionic liquids
References
7. Future outlook
7.1 Structural characteristics and dynamic stability mechanism of ionic liquids
7.2 Action mechanism and regulation law of ionic liquids in process intensification
7.3 The development of the chemical process for ionic liquids
References
Index

前言/序言

Chemical industry is a significant industry that contributes to the national economic development and a typical high-energy consuming industry. Chemical process enhancement is an effective means to solve the contradiction between development and pollution brought by process industry. It is also an important measure for the sus- tainable development of chemical processes. At present, most chemical processes involve multiphase complex reactions and separation systems such as gas-liquid, liquid- liquid, and gas-liquid-solid. However, they are still limited to traditional static, offline, and macroscopic research modes, and cannot achieve in-depth analysis of reaction and transfer behavior at the micro level. There are many methods for intensifying chemical processes, among which medium strengthening is one of the most effective means. One of the important challenges facing scientists is to advance chemical research from the existing macro static level to the micro level, and achieve a fundamental break- through in traditional chemical processes.

Ionic liquid is a green medium composed of anions and cations,  appears as a liq-uid at room temperature. It can serve as a medium to replace traditional organic sol-vents for chemical reactions and separation, achieving the greening of chemical processes. After decades of development, ionic liquid has now reached the stage of industrial practice, attracting high attention from academia and industry, and becoming an international scientific frontier and research hotspot for chemical process enhance- ment. Especially in recent years, the understanding of the scientific essence of ionic liquid structures has been continuously deepened, forming the scientific foundation for enhancing the chemical process of ionic liquids.

This book focuses on the chemical process of intensifying the ionic liquid structure. Starting from the interaction and interface of ionic liquids, it elaborates on the pro- cesses of strengthening reactions and separation, photo and electrochemical processes with ionic liquids, synthesis of ionic liquid-based materials, and so on. On the basis of original, further introduces the latest research achievements at home and abroad, analyzes and discusses them with some typical examples. It is a comprehensive monograph that introduces the structure control and process intensification of ionic liquids.

This book was organized and written by academician Suojiang Zhang of the Institute of Process Engineering, Chinese Academy of Sciences (CAS), and proposed the writing idea and outline. This book is divided into seven chapters, and the authors who participated in this book are as follows:

Chapter 1 Introduction

Sections 1-3  Suojiang Zhang, Institute of Process Engineering, CAS 

Yao Li, Institute of Process Engineering, CAS

Chapter 2 Interaction and interface of ionic liquids

Section 1  Hongyan He, Institute of Process Engineering, CAS 

Section 2  Zhiping Liu, Beijing University of Chemical Technology 

Sections 3-4  Hongyan He, Institute of Process Engineering, CAS

Yanlei Wang, Institute of Process Engineering, CAS 

Weilu Ding, Institute of Process Engineering, CAS

Section 5  Zhiping Liu, Beijing University of Chemical Technology

Chapter 3 Ionic liquids intensify reaction process

Section 1  Jiayu Xin, Institute of Process Engineering, CAS

Sections 2-3  Juan Zhang, Hebei University of Science and Technology 

Section 4  Yuhong Huang, Institute of Process Engineering, CAS

Xuan Zhang, Institute of Process Engineering, CAS 

Boxia Guo, Institute of Process Engineering, CAS

Section 5  Ying Kang, Liaoning University

Dawei Fang, Liaoning University

Chapter 4 Ionic liquids intensify separation process

Section 1  Junfeng Wang